Laboratory testing to produce intergranular stress corrosion cracking (IGSCC) of Alloy 600 steam generator tubing in primary water environments can require lengthy exposure times, even at a temperature of 360 C (680 F). Recent testing of Alloy 600 in hydrogen-containing steam at 400 C (750 F) has shown the characteristic IGSCC phenomenology, but with about a tenfold decrease in the IGSCC initiation time compared to the time in high-purity, hydrogen-containing water at 360 C. The IGSCC behavior depends both on the steam pressure/density and the hydrogen partial pressure. The role of microstructural variables, including grain boundary carbide precipitation and heat treatment, is similar in water and steam.

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