Caustic soda (NaOH) production is related to a very aggressive environment. The use of special alloys is essential, such as UNS N02200 and duplex UNS S2906 in the first evaporator effect through diaphragm route. A similar environment compared both different materials and concluded that UNS S32906 had performed better than UNS N02200 under boiling 50%NaOH and addition of NaCl and ClO3. This present study referred to 45%NaOH and 5%NaCl at 141,3°C in the tube side. After six months, UNS S32906 sample was intact while UNS N02200 showed general corrosion attack. It consequently represented a cost-effective solution to implement the duplex stainless steel after several evidence of its equipment life cycle improvement.

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